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Potential ecological risk assessment of heavy metals in the reclaimed soil of Xiaoyi Bauxite Mine |
NIE Xingshan |
Shanxi Institute of Soil and Water Conversation Science, 030045, Taiyuan, China |
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Abstract [Background] Mineral is a key resource for social and economic development. However, environment issues from mining are more and more serious. Shanxi is a resource province, a lot of land were destructed during the mining, and should be reclaimed after mining. In order to understand the potential pollution characteristics and the pollution risk of heavy metals in reclaimed soil, the heavy metal elements Cd, Cr, Cu, Pb, As, Ni and Zn of reclaimed soils at Xiaoyi Bauxite Mine were analyzed.[Methods] On April in 2016, 6 groups and 18 soil samples were collected from reclaimed land of in Xihedi village where corn was planted. Soil samples were passed 100 mesh sieves after natural air-drying. Then seven heavy mental elements were measured using inductively-coupled plasma spectrometer after digestion and decomposition by nitric acid-perchloric acid-hydrofluoric acid. Based on the heavy mental contents, pollution degree and potential ecological risk of heavy mental were evaluated using Hakanson ecological risk index.[Results] The mean content values of Cd, Cr, Cu, Pb, Ni and Zn were respectively 5.19, 40.47, 2.65, 65.13, 8.64, 13.05 and 28.98 mg/kg. The Cd was higher than 0.45 mg/kg that is the national second standard, while others were lesser. Mainly pollution element was Cd, and all 7 element contents exceeded the background values, and exited accumulated effects. The main pollution resource was from reclaimed soil, agricultural actions, dust precipitation and other anthropogenic activities in the mine area. The contents of Cu, Pb, and Ni had higher difference than that of As, Cr, Zn and Cd at different sampling places. The contents of Cd, Cr, and As have significant correlations, and presented combined pollution. The mean pollution index of Cd, Cr, Cu, Pb, Ni and Zn were respectively 11.54, 0.20, 0.02, 0.82, 0.28, 0.15 and 0.11, and as Cd > Pb > As > Cr > Ni > Zn > Cu. The Cd was at the highest pollution level, while other elements were in the lower. The comprehensive pollution index was 1.88, and at middle comprehensive pollution degree. The mean potential ecological risk index (RI) of Cd, Cr, Cu, Pb, Ni and Zn were respectively 230.87, 0.40, 0.13, 4.07, 1.44, 1.45 and 0.03, and as Cd > Pb > Ni > As > Cr > Cu > Zn. The ecological risk index was 238.39, and at the medium ecological risk level.[Conclusions] The reclaimed soil in Xiaoyi Bauxite Mine is in medium grade pollution risk, and mainly pollution element was Cd. Element Cd, Cs and As have higher homology than other elements. We should pay enough attentions to control and cut down the input of pollution sources, reduce the risk of pollution, especially the input of Cd. Hakanson ecological risk index method could magnify the evaluation result, but it could increase the attention about pollution risk.
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Received: 08 February 2017
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